IS Chemical Technology--hazard

Risk Phrases

Indication of Particular Risks

R1:	Explosive when dry
2:	Risk of explosion by shock, friction, fire or other sources of ignition
3:	Extreme risk of explosion by shock, friction, fire or other sources of ignition
4:	Forms very sensitive explosive metallic compounds
5:	Heating may cause an explosion
6:	Explosive with or without contact with air
7:	May cause fire
8:	Contact with combustible material may cause fire
9:	Explosive when mixed with combustible material
10:	Flammable
11:	Highly Flammable
12:	Extremely Flammable
14:	Reacts violently with water
15:	Contact with water liberates extremely flammable gases
16:	Explosive when mixed with oxidizing substances
17:	Spontaneously flammable in air
18:	In use may form flammable/explosive vapor-air mixture
19:	May form explosive peroxides
20:	Harmful by inhalation
21:	Harmful in contact with skin
22:	Harmful if swallowed
23:	Toxic by inhalation
24:	Toxic in contact with skin
25:	Toxic if swallowed
26:	Very Toxic by inhalation
27:	Very Toxic in contact with skin
28:	Very Toxic if swallowed
29:	Contact with water liberates toxic gas
30:	Can become highly flammable in use
31:	Contact with acids liberates toxic gas
32:	Contact with acids liberates very toxic gas
33:	Danger of cumulative effects
34:	Causes burns

35:	Causes severe burns
36:	Irritating to the eyes
37:	Irritating to the respiratory system
38:	Irritating to the skin
39:	Danger of very serious irreversible effects
40:	Limited evidence of a carcinogenic effect
41:	Risk of serious damage to eyes
42:	May cause sensitization by inhalation
43:	May cause sensitization by skin contact
44:	Risk of explosion if heated under confinement
45:	May cause cancer
46:	May cause heritable genetic damage
48:	Danger of serious damage to health by prolonged exposure
49:	May cause cancer by inhalation
50:	Very Toxic to aquatic organisms
51:	Toxic to aquatic organisms
52:	Harmful to aquatic organisms
53:	May cause long-term adverse effects in the aquatic environment
54:	Toxic to flora
55:	Toxic to fauna
56:	Toxic to soil organisms
57:	Toxic to bees
58:	May cause long-term adverse effects in the environment
59:	Dangerous for the ozone layer
60:	May impair fertility
61:	May cause harm to the unborn child
62:	Possible risk of impaired fertility
63:	Possible risk of harm to the unborn child
64:	May cause harm to breast-fed babies
65:	Harmful: May cause lung damage if swallowed
66:	Repeated exposure may cause skin dryness or cracking
67:	Vapors may cause drowsiness and dizziness
68:	Possible risk of irreversible effects

Risk Phrases

Combination of Particular Risks

14/15:	Reacts violently with water, liberating extremely flammable gases
15/29:	Contact with water liberates toxic, extremely flammable gas
20/21:	Harmful by inhalation and in contact with skin
20/21/22:	Harmful by inhalation, in contact with skin and if swallowed
20/22:	Harmful by inhalation and if swallowed
21/22:	Harmful in contact with skin and if swallowed
23/24:	Toxic by inhalation and in contact with skin
23/24/25:	Toxic by inhalation, in contact with skin and if swallowed
23/25:	Toxic by inhalation and if swallowed
24/25:	Toxic in contact with skin and if swallowed
26/27:	Very Toxic by inhalation and in contact with skin
26/27/28:	Very Toxic by inhalation, in contact with skin and if swallowed
26/28:	Very Toxic by inhalation and if swallowed
27/28:	Very Toxic in contact with skin and if swallowed
36/37:	Irritating to eyes and respiratory system
36/37/38:	Irritating to eyes, respiratory system and skin
36/38:	Irritating to eyes and skin
37/38:	Irritating to respiratory system and skin
39/23:	Toxic: danger of very serious irreversible effects through inhalation
39/23/24:	Toxic: danger of very serious irreversible effects through inhalation in contact with skin
39/23/24/25:	Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/23/25:	Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/24:	Toxic: danger of very serious irreversible effects in contact with skin
39/24/25:	Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/25:	Toxic: danger of very serious irreversible effects if swallowed
39/26:	Very Toxic: danger of very serious irreversible effects through inhalation
39/26/27:	Very Toxic: danger of very serious irreversible effects through inhalation and in contact with skin
39/26/27/28:	Very Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
39/26/28:	Very Toxic: danger of very serious irreversible effects through inhalation and if swallowed
39/27:	Very Toxic: danger of very serious irreversible effects in contact with skin
39/27/28:	Very Toxic: danger of very serious irreversible effects in contact with skin and if swallowed
39/28:	Very Toxic: danger of very serious irreversible effects if swallowed
42/43:	May cause sensitization by inhalation and skin contact

48/20:	Harmful: danger of serious damage to health by prolonged exposure through inhalation
48/20/21:	Harmful: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/20/21/22:	Harmful: danger of serious damage to health by prolonged exposure through inhalation, and in contact with skin and if swallowed
48/20/22:	Harmful: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/21:	Harmful: danger of serious damage to health by prolonged exposure in contact with skin
48/21/22:	Harmful: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/22:	Harmful: danger of serious damage to health by prolonged exposure if swallowed
48/23:	Toxic: danger of serious damage to health by prolonged exposure through inhalation
48/23/24:	Toxic: danger of serious damage to health by prolonged exposure through inhalation and in contact with skin
48/23/24/25:	Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed
48/23/25:	Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed
48/24:	Toxic: danger of serious damage to health by prolonged exposure in contact with skin
48/24/25:	Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
48/25:	Toxic: danger of serious damage to health by prolonged exposure if swallowed
50/53:	Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
51/53:	Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
52/53:	Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
68/20:	Harmful: possible risk of irreversible effects through inhalation
68/20/21:	Harmful: possible risk of irreversible effects through inhalation and in contact with skin
68/20/21/22:	Harmful: possible risk of irreversible effects through inhalation, in contact with skin and if swallowed
68/20/22:	Harmful: possible risk of irreversible effects through inhalation and if swallowed
68/22:	Harmful: possible risk of irreversible effects if swallowed
68/21:	Harmful: possible risk of irreversible effects in contact with skin
68/21/22:	Harmful: possible risk of irreversible effects in contact with skin and if swallowed
68/22:	Harmful: possible risk of irreversible effects if swallowed

Safety Phrases

Indication of Safety Precautions

S1:	Keep locked up
2:	Keep out of the reach of children
3:	Keep in a cool place
4:	Keep away from living quarters
5:	Keep contents under ... (appropriate liquid to be specified by the manufacturer)
6:	Keep under ... (inert gas to be specified by the manufacturer)
7:	Keep container tightly closed
8:	Keep container dry
9:	Keep container in a well-ventilated place
12:	Do not keep the container sealed
13:	Keep away from food, drink and animal feeding stuffs
14:	Keep away from ... (incompatible materials to be indicated by the manufacturer)
15:	Keep away from heat
16:	Keep away from sources of ignition - No smoking
17:	Keep away from combustible material
18:	Handle and open container with care
20:	When using, do not eat or drink
21:	When using, do not smoke
22:	Do not breathe dust
23:	Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24:	Avoid contact with skin
25:	Avoid contact with eyes
26:	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27:	Take off immediately all contaminated clothing
28:	After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
29:	Do not empty into drains
30:	Never add water to this product
33:	Take precautionary measures against static discharges

35:	This material and its container must be disposed of in a safe way
36:	Wear suitable protective clothing

37:	Wear suitable gloves
38:	In case of insufficient ventilation, wear suitable respiratory equipment
39:	Wear eye/face protection
40:	To clean the floor and all objects contaminated by this material use ... (to be specified by the manufacturer)
41:	In case of fire and/or explosion do not breathe fumes
42:	During fumigation/spraying wear suitable respiratory equipment (appropriate wording to be specified)
43:	In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45:	In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
46:	If swallowed, seek medical advice immediately and show this container or label
47:	Keep at temperature not exceeding ... E C (to be specified by the manufacturer)
48:	Keep wetted with ... (appropriate material to be specified by the manufacturer)
49:	Keep only in the original container
50:	Do not mix with ... (to be specified by the manufacturer)
51:	Use only in well-ventilated areas
52:	Not recommended for interior use on large surface areas
53:	Avoid exposure - obtain special instruction before use
56:	Dispose of this material and its container to hazardous or special waste collection point
57:	Use appropriate container to avoid environmental contamination
59:	Refer to manufacturer/supplier for information on recovery/recycling
60:	This material and/or its container must be disposed of as hazardous waste
61:	Avoid release to the environment. Refer to special instructions safety data sheet
62:	If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label
63:	In case of accident by inhalation, remove casualty to fresh air and keep at rest
64:	If swallowed, rinse mouth with water (only if the person is conscious)

Safety Phrases

Combination of Safety Precautions

1/2:	Keep locked up and out of the reach of children
3/7:	Keep container tightly closed in a cool place
3/9/14:	Keep in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
3/9/14/49:	Keep only in the original container in a cool well-ventilated place away from ... (incompatible materials to be indicated by manufacturer)
3/9/49:	Keep only in the original container in a cool well-ventilated place
3/14:	Keep in a cool place away from ... (incompatible materials to be indicated by the manufacturer)
7/8:	Keep container tightly closed and dry
7/9:	Keep container tightly closed and in a well-ventilated place
7/47:	Keep container tightly closed and at a temperature not exceeding ... °C (to be specified by manufacturer)
20/21:	When using, do not eat, drink or smoke

24/25:	Avoid contact with skin and eyes
27/28:	After contact with skin, take off immediately all contaminated clothing and wash imediately with plenty of.... (to be specified by the manufacturer)
29/35:	Do not empty into drains, dispose of this container and it's material in a safe way
29/56:	Do not empty into drains, dispose of this material and its container to hazardous or special waste-collection point
36/37:	Wear suitable protective clothing and gloves
36/37/39:	Wear suitable protective clothing, gloves and eye/face protection
36/39:	Wear suitable protective clothing and eye/face protection
37/39:	Wear suitable gloves and eye/face protection
47/49:	Keep only in the original container at temperature not exceeding ... °C (to be specified by manufacturer)

FLUKA BRAND F CODES

F 1 Sensitive to air and humidity.
F 2 Sensitive to air and CO2.
F 3 Hygroscopic.
F 4 Do not heat over …°C.
1 = 10 °C
2 = 20 °C
3 = 30 °C
4 = 40 °C
5 = 50 °C
6 = 60 °C
7 = 70 °C
8 = 80 °C
9 = 90 °C
10 = 100 °C
11 = 110 °C
12 = 120 °C
13 = 130 °C
14 = 140 °C
15 = 150 °C

F 5 Dry material may explode.
F 6 Reacts with acids.
F 7 Keep under CO2.
F 8 Photosensitive.
F 9 Keep under nitrogen.
F 10 Keep under argon.
F 11 Keep under inert gas.
F 12 Shake before use.
F 13 Malodorous.
F 14 Carefully observe warning label.
F 15 Limited shelf life.
F 16 Decomposes easily.
F 17 May decompose by explosion.
F 18 Must be handled by instructed people only.
F 19 Lachrymator.
F 20 Not to be swallowed.
F 21 Sensitive to humidity.
F 22 Keep dust-free in the dark.
F 23 Sensitive to air.

F 24 Spontaneously flammable with alcohol.
F 25 Keep under CO.
F 26 Before distillation test for absence of peroxides.
F 27 Cool before opening.
F 28 May become cloudy (Polyformaldehyde).
F 29 Spontaneously flammable when dry.
F 30 Sediment unavoidable.
F 31 Do not puncture.
F 32 Avoid contact with heavy metal salts
especially iron salts.
F 33 Causes fall in blood pressure.
F 34 Sensitive to CO2.
F 35 Narcotic effects.
F 36 Extremely sensitive to air.

PICTOGRAMS AND HAZARD CODES

Biohazard

F	Highly Flammable
F+	Extremely Flammable

Oxidizing

Corrosive

Xn	Harmful
Xi	Irritant

Radioactive

Explosive

Dangerous for the
environment

T	Toxic
T+	Very Toxic